Unusual Allylpalladium Carboxylate Complexes: Identification of the Resting State of Catalytic Enantioselective Decarboxylative Allylic Alkylation Reactions of Ketones | Zendy

Sherden Nathaniel H. | Zendy; Behenna Douglas C. | Zendy; Virgil Scott C. | Zendy; Stoltz Brian M. | Zendy

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Unusual Allylpalladium Carboxylate Complexes: Identification of the Resting State of Catalytic Enantioselective Decarboxylative Allylic Alkylation Reactions of Ketones

Author(s) -

Sherden Nathaniel H.,

Behenna Douglas C.,

Virgil Scott C.,

Stoltz Brian M.

Publication year - 2009

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200902575

Subject(s) - enantioselective synthesis , chemistry , tsuji–trost reaction , alkylation , catalysis , allylic rearrangement , combinatorial chemistry , stereochemistry , medicinal chemistry , organic chemistry

Prickelnd! Die enantioselektive palladiumkatalysierte decarboxylierende Alkylierung von Ketonenolaten verläuft über η 1 ‐σ‐Allylpalladium‐Carboxylat‐Komplexe wie 1 (Pd gelb, O rot, N blau, P violett) durch langsamen CO 2 ‐Verlust. An Brausepulver erinnert das Verhalten unreiner Proben von 1 , die im festen Zustand ein Gas (vermutlich CO 2 ) ausstoßen und in Lösung aufschäumen.

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