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Rhodium‐Catalyzed Asymmetric Enyne Cycloisomerization of Terminal Alkynes and Formal Total Synthesis of (−)‐Platensimycin
Author(s) -
Nicolaou K. C.,
Li Ang,
Ellery Shelby P.,
Edmonds David J.
Publication year - 2009
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200901992
Subject(s) - cycloisomerization , chemistry , rhodium , enyne , total synthesis , stereochemistry , schema (genetic algorithms) , catalysis , combinatorial chemistry , computer science , organic chemistry , information retrieval
Effizient und direkt : Die Titelreaktion wird vorgestellt und für eine formale Totalsynthese von (−)‐Platensimycin genutzt (siehe Schema; Ts= para ‐Toluolsulfonyl, binap=2,2′‐Bis(diphenylphosphanyl)‐1,1′‐binaphthalin).
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