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Patterned Monolayers of Neutral and Charged Functionalized Manganese Arene Complexes on a Highly Ordered Pyrolytic Graphite Surface
Author(s) -
Kim Sang Bok,
Pike Robert D.,
D'Acchioli Jason S.,
Walder Brennan J.,
Carpenter Gene B.,
Sweigart Dwight A.
Publication year - 2009
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200805760
Subject(s) - chemistry , monolayer , highly oriented pyrolytic graphite , manganese , graphite , pyrolytic carbon , crystallography , organic chemistry , pyrolysis , biochemistry
Abstract Komplex als Muster : Die Arenmangantricarbonylkomplexe [Mn(η 5 ‐2,5‐Didodecoxy‐1,4‐semichinon) (CO) 3 ] und [Mn(η 6 ‐1,4‐Dioctyloxybenzol)(CO) 3 ] BF 4 bilden Monoschichten auf hoch geordneten Graphitoberflächen (HOPG). Wasserstoffbrücken, hydrophobe und elektrostatische Wechselwirkungen sorgen dafür, dass zweidimensionale Muster von Manganatomen oder ‐ionen resultieren.

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