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A Supramolecularly Assisted Transformation of Block‐Copolymer Micelles into Nanotubes
Author(s) -
Kim Sung Ho,
Nederberg Fredrik,
Jakobs Robert,
Tan Jeremy P. K.,
Fukushima Kazuki,
Nelson Alshakim,
Meijer E. W.,
Yang Yi Yan,
Hedrick James L.
Publication year - 2009
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200805414
Subject(s) - copolymer , micelle , chemistry , peg ratio , transformation (genetics) , polymer chemistry , block (permutation group theory) , polymer , organic chemistry , biochemistry , mathematics , finance , aqueous solution , economics , gene , geometry
Einmal um den Block : Führt man eine starre wasserstoffbrückenbildende Benzamid‐Einheit zwischen die Polymerblöcke in Poly(ethylenglycol)(PEG)‐(Thio)harnstoff‐Poly( L ‐Lactid)(PLLA)‐Blockcopolymeren ein, so ändert sich deren Morphologie: Statt sphärischer Micellen, wie sie von PEG‐PLLA‐Diblockcopolymeren gebildet werden, entstehen Nanoröhren.

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