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A Niobium‐Mediated Cycle Producing Phosphorus‐Rich Organic Molecules from White Phosphorus (P 4 ) through Activation, Functionalization, and Transfer Reactions
Author(s) -
Cossairt Brandi M.,
Cummins Christopher C.
Publication year - 2008
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200803971
Subject(s) - white phosphorus , surface modification , chemistry , molecule , phosphorus , niobium , organic chemistry
PROM'te Synthese : Die niobvermittelte Aggregation von zwei Molekülen weißen Phosphors führt zu reaktiven Nb 2 ‐koordinierten P 8 ‐Clustern, die z. B. in Diels‐Alder‐Reaktionen umgesetzt werden können und somit einen Zugang zu phosphorreichen organischen Molekülen (PROMs) öffnen (siehe Schema; orange P, weiß C).

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