cis ‐Selective Single‐Cleavage Skeletal Rearrangement of 1,6‐Enynes Reveals the Multifaceted Character of the Intermediates in Metal‐Catalyzed Cycloisomerizations | Zendy

JiménezNúñez Eloísa | Zendy; Claverie Christelle K. | Zendy; Bour Christophe | Zendy; Cárdenas Diego J. | Zendy; Echavarren Antonio M. | Zendy

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cis ‐Selective Single‐Cleavage Skeletal Rearrangement of 1,6‐Enynes Reveals the Multifaceted Character of the Intermediates in Metal‐Catalyzed Cycloisomerizations

Author(s) -

JiménezNúñez Eloísa,

Claverie Christelle K.,

Bour Christophe,

Cárdenas Diego J.,

Echavarren Antonio M.

Publication year - 2008

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200803269

Subject(s) - catalysis , chemistry , cleavage (geology) , stereochemistry , schema (genetic algorithms) , metal , computer science , organic chemistry , biology , information retrieval , fracture (geology) , paleontology

Gerüstbau mit Edelmetallen : Gold‐ und Platinkatalysatoren vermitteln die Titelreaktion von 1,6‐Eninen (siehe Schema: [M]=Metallkatalysator, Z=C(CO 2 Me) 2 , R=elektronenschiebende Gruppe). Für diese Umwandlung wird ein offenes carbokationisches Intermediat vorgeschlagen.

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