Oxygenation of a Me 2 Zn/α‐Diimine System: A Unique Zinc Methylperoxide Cluster and Evidence for Its Sequential Decomposition Pathways | Zendy

Lewiński Janusz | Zendy; Suwała Karolina | Zendy; Kubisiak Marcin | Zendy; Ochal Zbigniew | Zendy; Justyniak Iwona | Zendy; Lipkowski Janusz | Zendy

Premium

Oxygenation of a Me 2 Zn/α‐Diimine System: A Unique Zinc Methylperoxide Cluster and Evidence for Its Sequential Decomposition Pathways

Author(s) -

Lewiński Janusz,

Suwała Karolina,

Kubisiak Marcin,

Ochal Zbigniew,

Justyniak Iwona,

Lipkowski Janusz

Publication year - 2008

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200803254

Subject(s) - diimine , decomposition , zinc , chemistry , cluster (spacecraft) , medicinal chemistry , stereochemistry , organic chemistry , computer science , catalysis , operating system

O, was für eine Reaktion : Die Oxygenierung von Me 2 Zn⋅ t Bu‐DAB ( t Bu‐DAB= 1,4‐Di‐ tert ‐butyl‐1,4‐diazabutadien) liefert das neuartige Oxo(methylperoxid)‐Cuban 1 , das entsprechende doppelt cubische Oxo(methoxid) 2 und das C‐C‐verknüpfte zweikernige Methoxid [(MeZn) 2 ( t Bu‐DAB‐DAB(H)‐ t Bu)(μ‐OMe)], dessen Bildung mit der Homolyse einer ZnO‐OMe‐Bindung beginnt.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research