Synthesis and Characterization of the Metal(I) Dimers [Ar′MMAr′]: Comparisons with Quintuple‐Bonded [Ar′CrCrAr′] | Zendy

Nguyen Tailuan | Zendy; Merrill W. Alexander | Zendy; Ni Chengbao | Zendy; Lei Hao | Zendy; Fettinger James C. | Zendy; Ellis Bobby D. | Zendy; Long Gary J. | Zendy; Brynda Marcin | Zendy; Power Philip P. | Zendy

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Synthesis and Characterization of the Metal(I) Dimers [Ar′MMAr′]: Comparisons with Quintuple‐Bonded [Ar′CrCrAr′]

Author(s) -

Nguyen Tailuan,

Merrill W. Alexander,

Ni Chengbao,

Lei Hao,

Fettinger James C.,

Ellis Bobby D.,

Long Gary J.,

Brynda Marcin,

Power Philip P.

Publication year - 2008

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200802657

Subject(s) - characterization (materials science) , chemistry , aryl , stereochemistry , nanotechnology , materials science , organic chemistry , alkyl

Deutlich unterscheiden sich die Eisen‐ und Cobaltanaloga der fünffach gebundenen Chromverbindung [Ar′CrCrAr′] (Ar′=C 6 H 3 ‐2,6‐(2,6‐ i Pr 2 C 6 H 3 ) 2 ) von dieser, wie kristallographische, magnetische und Dichtefunktionalstudien ergaben. Die Metall‐η 6 ‐Aryl‐Wechselwirkungen in [Ar′FeFeAr′] und [Ar′CoCoAr′] sind stärker, die Metall‐Metall‐Bindungen dagegen viel schwächer als in der Chromverbindung.

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