Towards Organocatalytic Polyketide Synthases with Diverse Electrophile Scope: Trifluoroethyl Thioesters as Nucleophiles in Organocatalytic Michael Reactions and Beyond | Zendy

Alonso Diego A. | Zendy; Kitagaki Shinji | Zendy; Utsumi Naoto | Zendy; Barbas Carlos F. | Zendy

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Towards Organocatalytic Polyketide Synthases with Diverse Electrophile Scope: Trifluoroethyl Thioesters as Nucleophiles in Organocatalytic Michael Reactions and Beyond

Author(s) -

Alonso Diego A.,

Kitagaki Shinji,

Utsumi Naoto,

Barbas Carlos F.

Publication year - 2008

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200801088

Subject(s) - polyketide , nucleophile , electrophile , chemistry , scope (computer science) , organocatalysis , michael reaction , stereochemistry , philosophy , catalysis , biochemistry , computer science , enantioselective synthesis , enzyme , programming language , biosynthesis

Vielseitige Esternucleophile: Trifluorethylthioester sind nicht nur effektive Nucleophile für die Titelreaktion (oben), sondern können durch Einstellen ihrer elektronischen Eigenschaften auch für Aldolreaktionen und Aminierungen genutzt werden (unten).

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