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Towards Organocatalytic Polyketide Synthases with Diverse Electrophile Scope: Trifluoroethyl Thioesters as Nucleophiles in Organocatalytic Michael Reactions and Beyond
Author(s) -
Alonso Diego A.,
Kitagaki Shinji,
Utsumi Naoto,
Barbas Carlos F.
Publication year - 2008
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200801088
Subject(s) - polyketide , nucleophile , electrophile , chemistry , scope (computer science) , organocatalysis , michael reaction , stereochemistry , philosophy , catalysis , biochemistry , computer science , enantioselective synthesis , enzyme , programming language , biosynthesis
Vielseitige Esternucleophile: Trifluorethylthioester sind nicht nur effektive Nucleophile für die Titelreaktion (oben), sondern können durch Einstellen ihrer elektronischen Eigenschaften auch für Aldolreaktionen und Aminierungen genutzt werden (unten).

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