Controlling the Activation of White Phosphorus: Formation of Phosphorous Acid and Ruthenium‐Coordinated 1‐Hydroxytriphosphane by Hydrolysis of Doubly Metalated P 4 | Zendy

Barbaro Pierluigi | Zendy; Di Vaira Massimo | Zendy; Peruzzini Maurizio | Zendy; Seniori Costantini Stefano | Zendy; Stoppioni Piero | Zendy

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Controlling the Activation of White Phosphorus: Formation of Phosphorous Acid and Ruthenium‐Coordinated 1‐Hydroxytriphosphane by Hydrolysis of Doubly Metalated P 4

Author(s) -

Barbaro Pierluigi,

Di Vaira Massimo,

Peruzzini Maurizio,

Seniori Costantini Stefano,

Stoppioni Piero

Publication year - 2008

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200800723

Subject(s) - phosphor , white phosphorus , chemistry , ruthenium , phosphorus , hydrolysis , medicinal chemistry , organic chemistry , materials science , catalysis , optoelectronics

Erfolgreiche Zähmung : Als Brückenligand zwischen zwei {CpRu(PPh 3 ) 2 }‐Einheiten reagiert weißer Phosphor (P 4 ) selektiv mit Wasser unter Bildung von Phosphorsäure (H 3 PO 3 ) und dem bisher unbekannten 1‐Hydroxytriphosphan (PH(OH)PHPH 2 ), das durch Koordination an die beiden Rutheniumzentren stabilisiert wird (siehe Schema).

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