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A Heterobimetallic Pd/La/Schiff Base Complex for anti ‐Selective Catalytic Asymmetric Nitroaldol Reactions and Applications to Short Syntheses of β‐Adrenoceptor Agonists
Author(s) -
Handa Shinya,
Nagawa Keita,
Sohtome Yoshihiro,
Matsunaga Shigeki,
Shibasaki Masakatsu
Publication year - 2008
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200705617
Subject(s) - schiff base , enantioselective synthesis , chemistry , stereochemistry , catalysis , organic chemistry
Passgenau für zwei Metalle : Die Kombination aus Pd und La in einem Schiff‐Base‐Liganden führt zu einer anti ‐selektiven katalytischen asymmetrischen Nitroaldolreaktion (siehe Schema). Mithilfe des Heterodimetallkatalysators gelingen kurze Synthesen von β‐Adrenozeptor‐Agonisten.

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