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A Zirconium Hydrazide as a Synthon for a Metallanitrene Equivalent: Atom‐by‐Atom Assembly of [EN 2 ] 2− Units (E=S, Se) by Chalcogen‐Atom Transfer in the Coordination Sphere of a Transition Metal
Author(s) -
Herrmann Heike,
Lloret Fillol Julio,
Wadepohl Hubert,
Gade Lutz H.
Publication year - 2007
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200703938
Subject(s) - synthon , atom (system on chip) , chemistry , chalcogen , stereochemistry , crystallography , computer science , embedded system
Stück für Stück : Die N‐N‐Bindungen von Hydraziden an Zirconiumzentren werden leicht gespalten. Diese Spezies reagieren daher wie Metallanitrene, sodass verbrückende Dinitridosulfat(IV)‐ und Dinitridoselenat(IV)‐Liganden Atom für Atom aufgebaut werden können (siehe Schema; TBS= t BuMe 2 Si).

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