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Star‐Burst Prisms with Cyclotriveratrylene‐Type Ligands: A [Pd 6 L 8 ] 12+ Stella Octangular Structure
Author(s) -
Ronson Tanya K.,
Fisher Julie,
Harding Lindsay P.,
Hardie Michaele J.
Publication year - 2007
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200703903
Subject(s) - stella (programming language) , chemistry , type (biology) , star (game theory) , radius , content (measure theory) , stereochemistry , crystallography , physics , computer science , mathematics , thermodynamics , ecology , mathematical analysis , astrophysics , biology , computer security
Fast sternförmig : Tris(isonicotinoyl)cyclotriguaiacylen bildet mit Pd(NO 3 ) 2 metallosupramolekulare [Pd 6 L 8 ] 12+ ‐Käfigverbindungen mit einem Durchmesser über 3 nm (siehe Bild). ESMS‐ und DOSY‐NMR‐Studien belegen, dass die achteckige Struktur mit einem hydrodynamischen Radius um 19 Å auch in Lösung vorliegt.

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