Exploiting Self‐Assembly for Ligand‐Scaffold Optimization: Substrate‐Tailored Ligands for Efficient Catalytic Asymmetric Hydroboration | Zendy

Moteki Shin A. | Zendy; Takacs James M. | Zendy

Premium

Exploiting Self‐Assembly for Ligand‐Scaffold Optimization: Substrate‐Tailored Ligands for Efficient Catalytic Asymmetric Hydroboration

Author(s) -

Moteki Shin A.,

Takacs James M.

Publication year - 2008

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200703127

Subject(s) - hydroboration , chemistry , substituent , stereochemistry , scaffold , ligand (biochemistry) , enantioselective synthesis , catalysis , combinatorial chemistry , substrate (aquarium) , organic chemistry , computer science , programming language , biochemistry , oceanography , receptor , geology

Eine Bibliothek aus selbstorganisierten Liganden ( SAL XY ) ergibt in der rhodiumkatalysierten asymmetrischen Hydroborierung breit gefächerte R / S ‐Verhältnisse (siehe Schema; nbd = 2,5‐Norbornadien, R* = chiraler Substituent). Durch Optimierung des Ligandengerüsts gelangt man zu maßgeschneiderten Liganden für die hoch regio‐ und enantioselektive Umwandlung zahlreicher ortho ‐substituierter Styrolderivate.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research