A “Star” Antiferromagnet: A Polymeric Iron(III) Acetate That Exhibits Both Spin Frustration and Long‐Range Magnetic Ordering | Zendy

Zheng YanZhen | Zendy; Tong MingLiang | Zendy; Xue Wei | Zendy; Zhang WeiXiong | Zendy; Chen XiaoMing | Zendy; Grandjean Fernande | Zendy; Long Gary J. | Zendy

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A “Star” Antiferromagnet: A Polymeric Iron(III) Acetate That Exhibits Both Spin Frustration and Long‐Range Magnetic Ordering

Author(s) -

Zheng YanZhen,

Tong MingLiang,

Xue Wei,

Zhang WeiXiong,

Chen XiaoMing,

Grandjean Fernande,

Long Gary J.

Publication year - 2007

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200701954

Subject(s) - frustration , antiferromagnetism , chemistry , condensed matter physics , crystallography , physics , materials science

Sternenbildung : Polymeres [Fe 3 (μ 3 ‐O)(μ‐OAc) 6 (H 2 O) 3 ][Fe 3 (μ 3 ‐O)μ‐OAc) 7.5 ] 2 ⋅7 H 2 O wird durch das Verknüpfen dreieckiger {Fe 3 (μ 3 ‐O)}‐Cluster über anti‐anti ‐verbrückende Acetatliganden hergestellt (siehe Bild; rot und blau: Fe, orangefarben: O). Spin‐Frustration und weitreichende magnetische Ordnung koexistieren in dieser Verbindung unterhalb von 4.5 K (siehe Graph).

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