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Addition of Alkenes to Deltahedral Zintl Clusters by Reaction with Alkynes: Synthesis and Structure of [FcCHCHGe 9 CHCHFc] 2− , an Organo‐Zintl–Organometallic Anion
Author(s) -
Hull Michael W.,
Sevov Slavi C.
Publication year - 2007
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200701950
Subject(s) - chemistry , group 2 organometallic chemistry , cluster (spacecraft) , zintl phase , crystallography , stereochemistry , polymer chemistry , crystal structure , molecule , organic chemistry , computer science , programming language
„Organischer Zintl“ : Die Reaktion von K 4 Ge 9 mit FcCCH in Ethylendiamin liefert den gezeigten Ge 9 ‐Cluster, in dem zwei Ferroceneinheiten über Doppelbindungen an den Cluster gebunden sind. Die Verbindung erweitert damit die noch neue Klasse von Organo‐Zintl‐Verbindungen.

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