Electrochemical and Photochemical Behavior of a Ruthenium(II) Complex Bearing Two Redox Sites as a Model for the NAD + /NADH Redox Couple | Zendy

Tannai Hidenori | Zendy; Koizumi Takeaki | Zendy; Wada Tohru | Zendy; Tanaka Koji | Zendy

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Electrochemical and Photochemical Behavior of a Ruthenium(II) Complex Bearing Two Redox Sites as a Model for the NAD + /NADH Redox Couple

Author(s) -

Tannai Hidenori,

Koizumi Takeaki,

Wada Tohru,

Tanaka Koji

Publication year - 2007

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200701204

Subject(s) - redox , ruthenium , chemistry , electrochemistry , ligand (biochemistry) , oxidation reduction , nad+ kinase , photochemistry , inorganic chemistry , catalysis , organic chemistry , biochemistry , electrode , receptor , enzyme

Vier ist die Zahl : Der einkernige Ruthenium(II)‐Komplex [ 1 ] 2+ wird durch elektrochemische und photochemische Redoxreaktionen in wässriger Lösung reversibel in die vierelektronenreduzierte Form [ 1 ‐H 4 ] 2+ überführt. Der 2,6‐Bis(benzo[ b ]‐1,5‐naphthyridin‐6‐yl)‐4‐ tert ‐butylpyridin‐Ligand fungiert dabei abwechselnd als Reservoir/Quelle für vier Elektronen oder vier Protonen.

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