A Multifunctional Light Switch: DNA Binding and Cleavage Properties of a Heterobimetallic Ruthenium–Rhenium Dipyridophenazine Complex | Zendy

Foxon Simon P. | Zendy; Phillips Tim | Zendy; Gill Martin R. | Zendy; Towrie Michael | Zendy; Parker Anthony W. | Zendy; Webb Michelle | Zendy; Thomas Jim A. | Zendy

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A Multifunctional Light Switch: DNA Binding and Cleavage Properties of a Heterobimetallic Ruthenium–Rhenium Dipyridophenazine Complex

Author(s) -

Foxon Simon P.,

Phillips Tim,

Gill Martin R.,

Towrie Michael,

Parker Anthony W.,

Webb Michelle,

Thomas Jim A.

Publication year - 2007

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200604837

Subject(s) - ruthenium , rhenium , cleavage (geology) , chemistry , dna , stereochemistry , combinatorial chemistry , photochemistry , materials science , catalysis , organic chemistry , biochemistry , fracture (geology) , composite material

Ein DNA‐Multifunktionswerkzeug : In photo‐ und biophysikalischen Studien erwies sich der abgebildete Heterozweikernkomplex [{Ru(tpm)(dppz)}(μ‐dpp[5]){ fac ‐(CO) 3 Re(dppz)}] 3+ sowohl als DNA‐„Lichtschalter“ als auch als direktes Spaltungsagens; tpm=Tris(1‐pyrazolyl)methan; dppz=Dipyrido[3,2‐ a :2′,3′‐ c ]phenazin; dpp[5]=4,4′‐Dipyridylpentan.

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