trans  Influences on Hypervalent Bonding of Aryl  λ  3 ‐Iodanes: Their Stabilities and Isodesmic Reactions of Benziodoxolones and Benziodazolones | Zendy

Ochiai Masahito | Zendy; Sueda Takuya | Zendy; Miyamoto Kazunori | Zendy; Kiprof Paul | Zendy; Zhdankin Viktor V. | Zendy

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trans Influences on Hypervalent Bonding of Aryl λ 3 ‐Iodanes: Their Stabilities and Isodesmic Reactions of Benziodoxolones and Benziodazolones

Author(s) -

Ochiai Masahito,

Sueda Takuya,

Miyamoto Kazunori,

Kiprof Paul,

Zhdankin Viktor V.

Publication year - 2006

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200603055

Subject(s) - hypervalent molecule , chemistry , monomer , isodesmic reaction , aryl , medicinal chemistry , polymer chemistry , organic chemistry , molecule , alkyl , polymer , reagent

Groß und klein oder zweimal mäßig : Beide Kombinationen von trans ‐Einflüssen der Substituenten begünstigen die Bildung hoch stabiler Aryl‐ λ 3 ‐iodane ArILL′ (Beispiele: Ph[I(OH)OTs], Ph[I(OAc) 2 ]). Trans ‐Einflüsse scheinen auch eine Erklärung dafür zu liefern, dass Iodosylbenzol eine oxoverbrückte polymere Zickzackstruktur hat, während Ph[I(OH) 2 ] monomer ist.

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