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Total Synthesis and Absolute Stereochemistry of Polygalolides A and B
Author(s) -
Nakamura Seiichi,
Sugano Yukihito,
Kikuchi Fumiaki,
Hashimoto Shunichi
Publication year - 2006
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200602030
Subject(s) - chemistry , stereochemistry , cycloaddition , total synthesis , ylide , ring (chemistry) , absolute configuration , organic chemistry , catalysis
Ring frei für Carbonyl‐Ylide : Die erste Totalsynthese von Polygalolid A ( 1 ) und B ( 2 ) nutzt eine Tandemsequenz aus Carbonyl‐Ylid‐Bildung und 1,3‐dipolarer Cycloaddition, um das charakteristische 5,10‐Dioxatricyclo[6.2.1.0]undecan‐Gerüst der Verbindungen in einem einzigen Schritt aufzubauen.

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