Synthesis of Triphosphorous Bidentate Phosphine–Phosphoramidite Ligands: Application in the Highly Enantioselective Hydrogenation of  ortho ‐Substituted Aryl Enamides | Zendy

Zhang Weicheng | Zendy; Zhang Xumu | Zendy

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Synthesis of Triphosphorous Bidentate Phosphine–Phosphoramidite Ligands: Application in the Highly Enantioselective Hydrogenation of ortho ‐Substituted Aryl Enamides

Author(s) -

Zhang Weicheng,

Zhang Xumu

Publication year - 2006

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200601501

Subject(s) - denticity , phosphoramidite , chemistry , phosphine , enantioselective synthesis , aryl , medicinal chemistry , combinatorial chemistry , stereochemistry , organic chemistry , catalysis , metal , dna , biochemistry , alkyl , oligonucleotide

Ein neues Paar : Eine neuartige Kombination von Phosphan‐ und Phosphoramiditeinheiten kennzeichnet die pseudo‐ C 2 ‐symmetrischen zweizähnigen Phosphan‐Phosphoramidit‐Liganden 1 . Ihre Verwendung in Rh‐katalysierten Hydrierungen liefert bisher unerreichte Enantioselektivitäten bei der Umsetzung von ortho ‐substituierten Arylenamiden und 1‐Naphthylenamid.

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