A Ferromagnetically Coupled Mn 19  Aggregate with a Record  S =83/2 Ground Spin State | Zendy

Ako Ayuk M. | Zendy; Hewitt Ian J. | Zendy; Mereacre Valeriu | Zendy; Clérac Rodolphe | Zendy; Wernsdorfer Wolfgang | Zendy; Anson Christopher E. | Zendy; Powell Annie K. | Zendy

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A Ferromagnetically Coupled Mn 19 Aggregate with a Record S =83/2 Ground Spin State

Author(s) -

Ako Ayuk M.,

Hewitt Ian J.,

Mereacre Valeriu,

Clérac Rodolphe,

Wernsdorfer Wolfgang,

Anson Christopher E.,

Powell Annie K.

Publication year - 2006

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200601467

Subject(s) - spins , hydroxymethyl , ground state , content (measure theory) , spin (aerodynamics) , aggregate (composite) , chemistry , crystallography , physics , condensed matter physics , stereochemistry , nanotechnology , atomic physics , materials science , thermodynamics , mathematics , mathematical analysis

Gut gemischt : Ein Grundzustandsspin von S =83/2 wurde für das gemischtvalente Manganaggregat [Mn III 12 Mn II 7 (μ 4 ‐O) 8 (μ 3 ,η 1 ‐N 3 ) 8 (HL) 12 (MeCN) 6 ] 2+ nachgewiesen (H 3 L=2,6‐Bis(hydroxymethyl)‐4‐methylphenol; der Kern ist in Polyederdarstellung gezeigt). Die Größe des Spins ist darauf zurückzuführen, dass alle Metallzentren ferromagnetisch koppeln.

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