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The CFTA Method: A Reliable Procedure for the Determination of the Absolute Configuration of Chiral Primary Amines by 1 H NMR Spectroscopic Analysis
Author(s) -
Takeuchi Yoshio,
Segawa Masaru,
Fujisawa Hidehito,
Omata Kenji,
Lodwig Siegfried N.,
Unkefer Clifford J.
Publication year - 2006
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200600157
Subject(s) - absolute configuration , chemistry , primary (astronomy) , computational chemistry , stereochemistry , physics , astronomy
Überraschend stabile antiperiplanare Konformere von CFTA‐Amiden bilden die Basis einer neuen und sehr zuverlässigen Methode, die absolute Konfiguration chiraler primärer Amine 1 H‐NMR‐spektroskopisch zu bestimmen (siehe Bild). CFTA=α‐Cyan‐α‐fluor‐ p ‐tolylessigsäure.
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