A Self‐Complementary Assembly of Metallamacrocycles Directed by RuCl⋅⋅⋅HN Hydrogen Bonds and Its Reversible Dichotomy by Halide Anions in Solution | Zendy

Park Young Jun | Zendy; Kim JikSoo | Zendy; Youm KyoungTae | Zendy; Lee NamKyu | Zendy; Ko Jaejung | Zendy; Park Hyeseo | Zendy; Jun MooJin | Zendy

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A Self‐Complementary Assembly of Metallamacrocycles Directed by RuCl⋅⋅⋅HN Hydrogen Bonds and Its Reversible Dichotomy by Halide Anions in Solution

Author(s) -

Park Young Jun,

Kim JikSoo,

Youm KyoungTae,

Lee NamKyu,

Ko Jaejung,

Park Hyeseo,

Jun MooJin

Publication year - 2006

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200600154

Subject(s) - halide , chemistry , hydrogen bond , molecule , medicinal chemistry , stereochemistry , inorganic chemistry , organic chemistry

Vorwärts und rückwärts : [RuCl 2 (PPh 3 ) 3 ], 1,3‐Bis(diphenylphosphanyl)propan und ein Amidoligand sind die Komponenten in der koordinationsgesteuerten Selbstorganisation zweier Ruthenamakrocyclen durch NH⋅⋅⋅ClRu‐, π⋅⋅⋅π‐ und CH⋅⋅⋅π‐Wechselwirkungen (siehe Bild; violett Ru, grün Cl, orange P, rot O, blau N, grau C, weiß H). Die reversible Dissoziation/Assoziation dieses Komplexes in Lösung wird durch Halogenid‐Ionen gesteuert.

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