Broadband Femtosecond Fluorescence Spectroscopy of [Ru(bpy) 3 ] 2+ | Zendy

Cannizzo Andrea | Zendy; van Mourik Frank | Zendy; Gawelda Wojciech | Zendy; Zgrablic Goran | Zendy; Bressler Christian | Zendy; Chergui Majed | Zendy

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Broadband Femtosecond Fluorescence Spectroscopy of [Ru(bpy) 3 ] 2+

Author(s) -

Cannizzo Andrea,

van Mourik Frank,

Gawelda Wojciech,

Zgrablic Goran,

Bressler Christian,

Chergui Majed

Publication year - 2006

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200600125

Subject(s) - intersystem crossing , femtosecond , spectroscopy , broadband , fluorescence , chemistry , fluorescence spectroscopy , analytical chemistry (journal) , crystallography , physics , atomic physics , excited state , optics , laser , singlet state , quantum mechanics , chromatography

Es kocht! Untersuchungen zur Femtosekundenfluoreszenz‐Aufwärtskonvertierung von [Ru(bpy) 3 ] 2+ in wässriger Lösung ergaben eine kurzlebige schwingungsangeregte („heiße“) Emission des Singulett‐Metall‐Ligand‐Charge‐Transfer‐Zustands mit ultraschnellem Intersystem Crossing (ca. 10 fs) bei konstanter Energie in den Triplettzustand (die Farben kennzeichnen die Lumineszenzintensität).

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