Molybdenum‐Mediated Alkyne Incorporation into an Iridaborane Framework—Release of the Iridacarborane from the Molybdenum Coordination Sphere through a Dissociative Equilibrium | Zendy

de Montigny Frédéric | Zendy; Macias Ramón | Zendy; Noll Bruce C. | Zendy; Fehlner Thomas P. | Zendy

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Molybdenum‐Mediated Alkyne Incorporation into an Iridaborane Framework—Release of the Iridacarborane from the Molybdenum Coordination Sphere through a Dissociative Equilibrium

Author(s) -

de Montigny Frédéric,

Macias Ramón,

Noll Bruce C.,

Fehlner Thomas P.

Publication year - 2006

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200504242

Subject(s) - molybdenum , chemistry , alkyne , coordination sphere , cyan , medicinal chemistry , stereochemistry , crystallography , inorganic chemistry , crystal structure , organic chemistry , catalysis , physics , optics

Chaperon‐Service : An die Insertion von zwei 2‐Butineinheiten in das Iridaboran [(Cp*IrH)B 4 H 9 ] unter Bildung von [Cp*Ir(B 3 H 3 C 4 Me 4 ){Mo(CO) 3 }] ( 1 ; gelb Ir, grün B, magenta Mo, schwarz C, rot O, cyan H) schließt sich ein Iridacarboran‐Mo(CO) 3 ‐Koordinationsgleichgewicht an; eine reduzierte Bindungsaffinität setzt das Iridacarboran [Cp*Ir(B 3 H 3 C 4 Me 4 )] ( 2 ) frei.

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