An Unprecedented Example of a Hetero‐trimetallic Main‐Group [L 2 Al 2 Ge 4 Li 2 S 7 ] Cluster Containing a Ge II Ge II  Donor–Acceptor Bond | Zendy

Yang Zhi | Zendy; Ma Xiaoli | Zendy; Oswald Rainer B. | Zendy; Roesky Herbert W. | Zendy; Cui Chunming | Zendy; Schmidt HansGeorg | Zendy; Noltemeyer Mathias | Zendy

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An Unprecedented Example of a Hetero‐trimetallic Main‐Group [L 2 Al 2 Ge 4 Li 2 S 7 ] Cluster Containing a Ge II Ge II Donor–Acceptor Bond

Author(s) -

Yang Zhi,

Ma Xiaoli,

Oswald Rainer B.,

Roesky Herbert W.,

Cui Chunming,

Schmidt HansGeorg,

Noltemeyer Mathias

Publication year - 2006

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200503940

Subject(s) - crystallography , cluster (spacecraft) , chemistry , group (periodic table) , physics , computer science , organic chemistry , programming language

Donor willkommen : Die Reaktion von [{LAl[(SLi) 2 (thf) 2 ]} 2 ] (L=HC(CMeNAr) 2 , Ar=2,6‐ i Pr 2 C 6 H 3 ) mit GeCl 2 ⋅Dioxan liefert den neuartigen Heterotrimetallcluster [L 2 Al 2 Ge 4 Li 2 S 7 ] mit einer Ge II →Ge II ‐Einheit und einer krabbenartigen Struktur (Al grau, Ge magenta, Li orange, S gelb, O grün, N blau). Dieser Cluster ist das erste aluminiumhaltige Heterotrimetallsulfid.

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