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Mild Ullmann‐Type Biaryl Ether Formation Reaction by Combination of ortho ‐Substituent and Ligand Effects
Author(s) -
Cai Qian,
Zou Benli,
Ma Dawei
Publication year - 2006
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200503538
Subject(s) - substituent , ullmann reaction , chemistry , ether , stereochemistry , medicinal chemistry , organic chemistry , copper
In einflussreicher Stellung : Ein starker Effekt des NHCOR‐Substituenten in ortho ‐Stellung und ein Ligandeneffekt bewirken gemeinsam, dass 2‐Halogenacetanilide bei Raumtemperatur in einer Ullmann‐Biarylsynthese reagieren (siehe Schema).

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