Lanthanide–Transition‐Metal Sandwich Framework Comprising {Cu 3 } Cluster Pillars and Layered Networks of {Er 36 } Wheels | Zendy

Cheng JianWen | Zendy; Zhang Jie | Zendy; Zheng ShouTian | Zendy; Zhang ManBo | Zendy; Yang GuoYu | Zendy

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Lanthanide–Transition‐Metal Sandwich Framework Comprising {Cu 3 } Cluster Pillars and Layered Networks of {Er 36 } Wheels

Author(s) -

Cheng JianWen,

Zhang Jie,

Zheng ShouTian,

Zhang ManBo,

Yang GuoYu

Publication year - 2005

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200502917

Subject(s) - lanthanide , cluster (spacecraft) , transition metal , key (lock) , materials science , nanotechnology , crystallography , chemistry , computer science , catalysis , computer network , operating system , ion , organic chemistry , biochemistry

Synergistische Koordination von Isonicotinat(ina)‐Liganden und 1,2‐Benzoldicarboxylat(bdc)‐Liganden unter Hydrothermalbedingungen führt zu zwei neuen Koordinationspolymeren, [Er 7 (μ 3 ‐O)(μ 3 ‐OH) 6 (bdc) 3 ](ina) 9 [Cu 3 X 4 ] (X=Cl, Br). [Er 36 (μ 3 ‐OH) 30 (μ 3 ‐O) 6 (bdc) 6 ] 54+ ‐Räder bauen 2D‐Schichten auf (siehe Bild), die durch [Cu 3 X 4 (ina) 6 ] 4− ‐Säulen zu einem 3D‐Netzwerk verknüpft werden.

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