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Gelation of Helical Polypeptide–Random Coil Diblock Copolymers by a Nanoribbon Mechanism
Author(s) -
Kim Kyoung Taek,
Park Chiyoung,
Vandermeulen Guido W. M.,
Rider David A.,
Kim Chulhee,
Winnik Mitchell A.,
Manners Ian
Publication year - 2005
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200502809
Subject(s) - copolymer , random coil , mechanism (biology) , electromagnetic coil , materials science , chemical physics , chemistry , crystallography , polymer , physics , circular dichroism , composite material , quantum mechanics
Diblockcopolymere aus dem helicalen Polypeptid Poly(γ‐benzyl‐ L ‐glutamat) und Zufallsknäuelpolymeren wie Polyferrocenylsilanen gelieren in verdünnter Lösung thermoreversibel (siehe Bild). Für die Selbstorganisation der Blockcopolymere aus helicalen Polypeptiden wird ein neuartiger Mechanismus vorgeschlagen.

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