Experimental Evidence for a Jahn–Teller Distortion in AuCl 3 | Zendy

Blackmore Ian J. | Zendy; Bridgeman Adam J. | Zendy; Harris Neil | Zendy; Holdaway Mark A. | Zendy; Rooms John F. | Zendy; Thompson Emma L. | Zendy; Young Nigel A. | Zendy

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Experimental Evidence for a Jahn–Teller Distortion in AuCl 3

Author(s) -

Blackmore Ian J.,

Bridgeman Adam J.,

Harris Neil,

Holdaway Mark A.,

Rooms John F.,

Thompson Emma L.,

Young Nigel A.

Publication year - 2005

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200502503

Subject(s) - extended x ray absorption fine structure , jahn–teller effect , distortion (music) , crystallography , physics , planar , absorption (acoustics) , trigonal crystal system , chemistry , nanotechnology , absorption spectroscopy , materials science , computer science , quantum mechanics , crystal structure , optics , ion , computer graphics (images) , optoelectronics , amplifier , cmos

Daten aus der Matrixisolations‐IR‐Spektroskopie , der elektronischen Absorption und der Au‐L 3 ‐Kanten‐EXAFS (extended X‐ray absorption fine structure) lieferten die ersten experimentellen Belege dafür, dass die Grundzustandsstruktur von AuCl 3 nicht D 3 h ‐symmetrisch (trigonal‐planar) ist, sondern eine Jahn‐Teller‐verzerrte T‐förmige Geometrie hat (siehe Bild).

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