Hydrogen‐Bonded Supramolecular Assemblies as Robust Templates in the Synthesis of Large Metal‐Coordinated Capsules | Zendy

McKinlay Robert M. | Zendy; Thallapally Praveen K. | Zendy; Cave Gareth W. V. | Zendy; Atwood Jerry L. | Zendy

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Hydrogen‐Bonded Supramolecular Assemblies as Robust Templates in the Synthesis of Large Metal‐Coordinated Capsules

Author(s) -

McKinlay Robert M.,

Thallapally Praveen K.,

Cave Gareth W. V.,

Atwood Jerry L.

Publication year - 2005

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200501491

Subject(s) - supramolecular chemistry , template , pyrogallol , chemistry , metal , polymer chemistry , stereochemistry , molecule , combinatorial chemistry , nanotechnology , materials science , organic chemistry

Ungewöhnliche H 2 O‐Kette : Große neutrale hexamere Koordinationskäfige [Ga 12 (H 2 O) 24 (C 40 H 42 O 12 ) 6 ⊂(Aceton) 8 (H 2 O) 6 ] werden aus sechs Pyrogallol[4]aren‐Liganden und zwölf Gallium( III )‐Ionen aufgebaut. Innerhalb der Kapselstruktur liegen zwei pseudo‐lineare wasserstoffverbrückte (H 2 O) 5 ‐Ketten vor (siehe Bild; Ga gold, O rot).

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