Reaction of Ruthenium Ethyne‐1,2‐diyl Compounds with Bis(trimethylsilyl)acetylene Complexes of Titanocene and Zirconocene: Remarkable Transfer of a C 2  Ligand | Zendy

Griffith Christopher S. | Zendy; Koutsantonis George A. | Zendy; Skelton Brian W. | Zendy; White Allan H. | Zendy

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Reaction of Ruthenium Ethyne‐1,2‐diyl Compounds with Bis(trimethylsilyl)acetylene Complexes of Titanocene and Zirconocene: Remarkable Transfer of a C 2 Ligand

Author(s) -

Griffith Christopher S.,

Koutsantonis George A.,

Skelton Brian W.,

White Allan H.

Publication year - 2005

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200500224

Subject(s) - chemistry , acetylene , ligand (biochemistry) , trimethylsilyl , metallacycle , ruthenium , polymer chemistry , metallocene , medicinal chemistry , stereochemistry , organic chemistry , x ray crystallography , polymerization , catalysis , receptor , biochemistry , physics , diffraction , optics , polymer

Transfer eines Kohlenstoffliganden : Verbindung 1 entsteht mit reaktiven Metall‐Ligand‐Fragmenten, die aus Gruppe‐4‐Metallocenen erzeugt werden. Tropfenweise Zugabe von ethanolischer HCl zu einer Lösung von 1 in Toluol liefert in einer als bislang unbekannt erachteten C‐C‐Verknüpfung den Komplex 2 .

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