Alkenylcarbene Ruthenium Arene Complexes as Initiators of Alkene Metathesis: An Enyne Creates a Catalyst that Promotes Its Selective Transformation | Zendy

Castarlenas Ricardo | Zendy; Eckert Matthieu | Zendy; Dixneuf Pierre H. | Zendy

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Alkenylcarbene Ruthenium Arene Complexes as Initiators of Alkene Metathesis: An Enyne Creates a Catalyst that Promotes Its Selective Transformation

Author(s) -

Castarlenas Ricardo,

Eckert Matthieu,

Dixneuf Pierre H.

Publication year - 2005

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200462865

Subject(s) - alkene , metathesis , ruthenium , chemistry , catalysis , enyne metathesis , enyne , stereochemistry , transformation (genetics) , combinatorial chemistry , organic chemistry , polymer , polymerization , biochemistry , gene

Ein Molekül erzeugt seinen Katalysator : [RuCl(aren)(PCy 3 )]OTf (z. B. 1 ) erzeugt mit Allyl‐ oder Propylpropargylethern in einer Metallo‐retro‐En‐Reaktion die Alkenylcarben‐Derivate 2 . Diese effizienten Ringschlussmetathese‐Katalysatoren wandeln Allylpropargylether in Alkenylcycloalkene und Diene in cyclische Alkene um (siehe Schema).

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