Electrochemical Hydrogenation of [Ru(bpy) 2 (napy‐ κN )(CO)] 2+ : Inhibition of Reductive RuCO Bond Cleavage by a Ruthenacycle | Zendy

Tomon Takashi | Zendy; Koizumi Takeaki | Zendy; Tanaka Koji | Zendy

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Electrochemical Hydrogenation of [Ru(bpy) 2 (napy‐ κN )(CO)] 2+ : Inhibition of Reductive RuCO Bond Cleavage by a Ruthenacycle

Author(s) -

Tomon Takashi,

Koizumi Takeaki,

Tanaka Koji

Publication year - 2005

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200462486

Subject(s) - chemistry , electrochemistry , ligand (biochemistry) , ruthenium , cleavage (geology) , bond cleavage , medicinal chemistry , stereochemistry , catalysis , combinatorial chemistry , organic chemistry , electrode , materials science , receptor , biochemistry , fracture (geology) , composite material

Die Reduktion von [Ru(bpy) 2 (napy‐ κN ) (CO)] 2+ ( 1 2+ ; napy=1,8‐Naphthyridin) bei −1.40 V in H 2 O liefert den fünfgliedrigen Metallacyclus 2 + , dessen Napy‐Ligand an der 4‐Position hydriert ist. Chemische oder elektrochemische Oxidation von 2 + führt mit nahezu quantitativer Ausbeute zurück zu 1 2+ .

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