A Double Iodoetherification of σ‐Symmetric Diene Acetals for Installing Four Stereogenic Centers in a Single Operation: Short Asymmetric Total Synthesis of Rubrenolide | Zendy

Fujioka Hiromichi | Zendy; Ohba Yusuke | Zendy; Hirose Hideki | Zendy; Murai Kenichi | Zendy; Kita Yasuyuki | Zendy

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A Double Iodoetherification of σ‐Symmetric Diene Acetals for Installing Four Stereogenic Centers in a Single Operation: Short Asymmetric Total Synthesis of Rubrenolide

Author(s) -

Fujioka Hiromichi,

Ohba Yusuke,

Hirose Hideki,

Murai Kenichi,

Kita Yasuyuki

Publication year - 2005

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200461584

Subject(s) - stereocenter , schema (genetic algorithms) , tetrahydrofuran , stereochemistry , chemistry , computer science , combinatorics , enantioselective synthesis , organic chemistry , information retrieval , mathematics , catalysis , solvent

Tetrahydrofuran‐Einheiten mit mehreren Chiralitätszentren entstehen hoch diastereoselektiv bei der im Schema gezeigten Eintopfreaktion aus σ‐symmetrischen Dienacetalen. Die Nüzlichkeit des Verfahrens belegt die ebenfalls beschriebene kurze asymmetrische Synthese von (+)‐Rubrenolid.

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