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Stereospecific, Enantioselective Allylation of α‐Hydrazono Esters by Using Allyltrichlorosilanes with BINAP Dioxides as Neutral‐Coordinate Organocatalysts
Author(s) -
Ogawa Chikako,
Sugiura Masaharu,
Kobayashi Shū
Publication year - 2004
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200461312
Subject(s) - enantioselective synthesis , stereospecificity , schema (genetic algorithms) , chemistry , stereochemistry , computer science , information retrieval , organic chemistry , catalysis
Mit ausgezeichneter Diastereo‐ und Enantioselektivität verläuft die Titelreaktion. ( E )‐Crotylsilane liefern syn ‐Addukte, ( Z )‐Crotylsilane dagegen anti ‐Addukte (siehe Schema).
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