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Surface‐Cap‐Mediated Host–Guest Chemistry of Semiconductor CdS: Intercalative Cation Accumulation around a Phenyl‐Capped CdS Cluster and Its Notable Effects on the Cluster Photoluminescence
Author(s) -
Hiratani Takayuki,
Konishi Katsuaki
Publication year - 2004
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200461190
Subject(s) - chemistry , intercalation (chemistry) , photoluminescence , cluster (spacecraft) , stereochemistry , crystallography , inorganic chemistry , materials science , optoelectronics , computer science , programming language
Licht an! Eine bemerkenswerte Photolumineszenzverstärkung wird bei der Intercalation von Cetyltrimethylammonium‐Kationen (CTA + ) zwischen die aromatischen Gruppen auf der Oberfläche eines Komplexes aus dem phenylüberdachten Halbleiter‐CdS‐Clustermolekül [Cd 10 S 4 (SPh) 12 ] ( 1 ) und Tetraoctylammoniumbromid (TOAB) beobachtet (siehe Schema).

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