Photoconversion of a Redox‐Active Self‐Assembled Monolayer: In Situ Probing of Photoinduced CO Dissociation from a Triruthenium Cluster Center on Gold | Zendy

Abe Masaaki | Zendy; Masuda Takuya | Zendy; Kondo Toshihiro | Zendy; Uosaki Kohei | Zendy; Sasaki Yoichi | Zendy

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Photoconversion of a Redox‐Active Self‐Assembled Monolayer: In Situ Probing of Photoinduced CO Dissociation from a Triruthenium Cluster Center on Gold

Author(s) -

Abe Masaaki,

Masuda Takuya,

Kondo Toshihiro,

Uosaki Kohei,

Sasaki Yoichi

Publication year - 2005

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200460651

Subject(s) - monolayer , dissociation (chemistry) , chemistry , cluster (spacecraft) , redox , in situ , center (category theory) , photochemistry , nanotechnology , crystallography , materials science , inorganic chemistry , computer science , organic chemistry , biochemistry , programming language

Photoempfindliche selbstorganisierte Monoschichten (self‐assembled monolayers, SAMs): Die erste durch Bestrahlung ausgelöste Umwandlung eines redoxaktiven molekularen Films gelang durch photochemische Anregung eines Ru 3 ‐Clusters mit CO‐Liganden auf einer Au(111)‐Elektrode. Dissoziation von CO führt sauber zu einer H 2 O‐terminierten SAM (siehe Bild).

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