Cationic Planar Chiral Palladium P,S Complexes as Highly Efficient Catalysts in the Enantioselective Ring Opening of Oxa‐ and Azabicyclic Alkenes | Zendy

Cabrera Silvia | Zendy; Gómez Arrayás Ramón | Zendy; Carretero Juan C. | Zendy

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Cationic Planar Chiral Palladium P,S Complexes as Highly Efficient Catalysts in the Enantioselective Ring Opening of Oxa‐ and Azabicyclic Alkenes

Author(s) -

Cabrera Silvia,

Gómez Arrayás Ramón,

Carretero Juan C.

Publication year - 2004

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200460087

Subject(s) - enantioselective synthesis , chemistry , cationic polymerization , palladium , ring (chemistry) , catalysis , stereochemistry , medicinal chemistry , organic chemistry

Niedrige Katalysatorbeladung , milde Reaktionsbedingungen, hohe Enantioselektivität und breite Anwendbarkeit kennzeichnen die durch kationische Methylpalladium( II )‐Komplexe von planar‐chiralen Fesulphos‐Liganden (Fesulphos=1‐Phosphanyl‐2‐sulfenylferrocen) katalysierte alkylierende Ringöffnung von Oxa‐ und Azabicycloalkenen mit Dialkylzinkreagentien (siehe Schema, Cy=Cyclohexyl, Ar F =3,5‐Bis(trifluormethyl)phenyl).

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