Cycloisomerization Promoted by the Combination of a Ruthenium–Carbene Catalyst and Trimethylsilyl Vinyl Ether, and its Application in The Synthesis of Heterocyclic Compounds: 3‐Methylene‐2,3‐dihydroindoles and 3‐Methylene‐2,3‐dihydrobenzofurans | Zendy

Terada Yukiyoshi | Zendy; Arisawa Mitsuhiro | Zendy; Nishida Atsushi | Zendy

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Cycloisomerization Promoted by the Combination of a Ruthenium–Carbene Catalyst and Trimethylsilyl Vinyl Ether, and its Application in The Synthesis of Heterocyclic Compounds: 3‐Methylene‐2,3‐dihydroindoles and 3‐Methylene‐2,3‐dihydrobenzofurans

Author(s) -

Terada Yukiyoshi,

Arisawa Mitsuhiro,

Nishida Atsushi

Publication year - 2004

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200454157

Subject(s) - chemistry , methylene , cycloisomerization , trimethylsilyl , carbene , catalysis , ruthenium , ether , vinyl ether , organic chemistry , medicinal chemistry , copolymer , polymer

Substituierte N‐ und O‐Heterocyclen wurden durch Cycloisomerisierung von Dienen mithilfe eines Rutheniumcarben‐Katalysators hergestellt. Die mit und ohne Trimethylsilyl(vinyl)ether erhaltenen Produkte sind unterschiedlich (siehe Schema, Cy=Cyclohexyl, Mes=2,4,6‐Trimethylphenyl, Ts= para ‐Toluolsulfonyl).

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