Premium
A New Dirhodium( II ) Carboxamidate Complex as a Chiral Lewis Acid Catalyst for Enantioselective Hetero‐Diels–Alder Reactions
Author(s) -
Anada Masahiro,
Washio Takuya,
Shimada Naoyuki,
Kitagaki Shinji,
Nakajima Makoto,
Shiro Motoo,
Hashimoto Shunichi
Publication year - 2004
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200453821
Subject(s) - enantioselective synthesis , chemistry , schema (genetic algorithms) , aldehyde , diels–alder reaction , lewis acids and bases , alder , catalysis , stereochemistry , organic chemistry , computer science , information retrieval , botany , biology
Hohe Enantioselektivitäten (bis zu 99 % ee ) und Umsatzzahlen (bis zu 48 000) wurden in der Hetero‐Diels‐Alder‐Reaktion diverser Aldehyde mit aktivierten Dienen in Gegenwart des Katalysators [Rh 2 ( S ‐bptpi) 4 ] erzielt (siehe Schema).
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom