Porous Organic–Inorganic Assemblies Constructed from Keggin Polyoxometalate Anions and Calix[4]arene–Na +  Complexes: Structures and Guest‐Sorption Profiles | Zendy

Ishii Yusuke | Zendy; Takenaka Yasumasa | Zendy; Konishi Katsuaki | Zendy

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Porous Organic–Inorganic Assemblies Constructed from Keggin Polyoxometalate Anions and Calix[4]arene–Na + Complexes: Structures and Guest‐Sorption Profiles

Author(s) -

Ishii Yusuke,

Takenaka Yasumasa,

Konishi Katsuaki

Publication year - 2004

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200453693

Subject(s) - polyoxometalate , sorption , chemistry , amphiphile , polymer chemistry , inorganic chemistry , crystallography , copolymer , organic chemistry , adsorption , catalysis , polymer

Amphiphile Porenwände erleichtern die reversible Sorption von kurzkettigen Alkoholen durch das mikroporöse organisch‐anorganische 1D‐Hybrid [ 1 ‐Na] 3 [PW 12 O 40 ], das aus dem Calix[4]aren‐Na + ‐Komplex 1 ‐Na + (R 1 =R 2 =H) und dem Polyoxowolframat‐Ion [PW 12 O 40 ] 3− aufgebaut ist. Das analoge, mit 2 ‐Na + (R 1 = t Bu, R 2 =CH 2 CO 2 Et) erhaltene Aggregat hat eine mikroporöse 3D‐Architektur.

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