Premium
Reaction‐Temperature‐Dependent Supramolecular Isomerism of Coordination Networks Based on the Organometallic Building Block [Cu I 2 (μ 2 ‐BQ)(μ 2 ‐OAc) 2 ]
Author(s) -
Masaoka Shigeyuki,
Tanaka Daisuke,
Nakanishi Yasunori,
Kitagawa Susumu
Publication year - 2004
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200353463
Subject(s) - synthon , supramolecular chemistry , chemistry , phase (matter) , block (permutation group theory) , group 2 organometallic chemistry , stereochemistry , combinatorial chemistry , medicinal chemistry , polymer chemistry , crystallography , organic chemistry , molecule , crystal structure , combinatorics , mathematics
Drei supramolekulare Isomere , [Cu ${{{{\rm {\rm I}}\hfill \atop 2\hfill}}}$ (μ 4 ‐BQ)(μ 2 ‐OAc) 2 ] n (α‐Phase), [Cu ${{{{\rm {\rm I}}\hfill \atop 2\hfill}}}$ (μ 3 ‐BQ)(μ 2 ‐OAc)(μ 3 ‐OAc)] n (β‐Phase) und [Cu ${{{{\rm {\rm I}}\hfill \atop 2\hfill}}}$ (μ 2 ‐BQ)(μ 3 ‐OAc) 2 ] n (γ Phase), kristallisieren unter Anwendung des gezeigten metallorganischen Bausteins – der zwei Typen supramolekularer Synthons enthält – aus dem gleichen Lösungsmittel. BQ=Benzochinon.