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A Water‐Soluble Tetranuclear Zr IV Compound Supported by the Kläui Tripodal Ligand: A Model of Zr IV in Aqueous Media
Author(s) -
Zhang QianFeng,
Lam Tony C. H.,
Chan Eddie Y. Y.,
Lo Samuel M. F.,
Williams Ian D.,
Leung WaHung
Publication year - 2004
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200353298
Subject(s) - phosphodiester bond , aqueous solution , chemistry , ligand (biochemistry) , aqueous medium , x ray crystallography , crystallography , polymer chemistry , stereochemistry , physics , diffraction , organic chemistry , receptor , rna , biochemistry , optics , gene
Wasserlöslich und stabil : Die Behandlung von Zirconylnitrat mit dem tripodalen Kläui‐Sauerstoffliganden in verdünnter Salpetersäure führt zu einer wasserlöslichen, vierkernigen hydroxoverbrückten Zr IV ‐Verbindung (siehe Bild; C grau, O rot, P lila, Co blau, Zr grün), die mit einem Phosphodiester zu einem Zr IV ‐Phosphat‐Cubancluster reagiert.

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