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Enantioselective H‐Atom Transfer Reactions: A New Methodology for the Synthesis of β 2 ‐Amino Acids
Author(s) -
Sibi Mukund P.,
Patil Kalyani
Publication year - 2004
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200353000
Subject(s) - enantioselective synthesis , chemistry , schema (genetic algorithms) , lewis acids and bases , atom (system on chip) , stereochemistry , combinatorial chemistry , computational chemistry , catalysis , organic chemistry , computer science , information retrieval , parallel computing
Ein radikaler Schritt : Die Addition von Radikalen an Aminoacrylate mit anschließendem H‐Atom‐Transfer in Gegenwart chiraler Lewis‐Säure‐Aktivatoren führt in hohen Ausbeuten zu enantiomerenreinen β 2 ‐Aminosäuren (siehe Schema).

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