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Asymmetric Induction of Three Consecutive Chiral Centers by Reactions of N ‐Enoylthioamides with Aldehydes
Author(s) -
Kataoka Tadashi,
Kinoshita Hironori,
Kinoshita Sayaka,
Osamura Takashi,
Watanabe Shinichi,
Iwamura Tatsunori,
Muraoka Osamu,
Tanabe Genzoh
Publication year - 2003
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200351106
Subject(s) - asymmetric induction , chemistry , enantioselective synthesis , combinatorial chemistry , stereochemistry , medicinal chemistry , organic chemistry , catalysis
Ein asymmetrisch substituiertes Brückenkopf‐C‐Atom , das an vier Heteroatome gebunden ist, enthalten die Tricyclen 1 , die diastereoselektiv bei der Reaktion von N ‐Cinnamoyl‐1,3‐oxazolin‐2‐thionen mit aromatischen Aldehyden in Gegenwart von BF 3 ⋅Et 2 O erhalten werden.
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