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Novel Azine Reactivity: Facile NN Bond Cleavage, CH Activation, and NN Coupling Mediated by Rh I
Author(s) -
Cohen Revital,
Rybtchinski Boris,
Gandelman Mark,
Shimon Linda J. W.,
Martin Jan M. L.,
Milstein David
Publication year - 2003
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200250571
Subject(s) - azine , chemistry , reactivity (psychology) , cleavage (geology) , bond cleavage , stereochemistry , medicinal chemistry , catalysis , materials science , organic chemistry , medicine , alternative medicine , pathology , fracture (geology) , composite material
Eine beispiellose Umsetzung : Distickstoff‐Rh‐Pinzettenkomplexe reagieren mit Azinen mäßig katalytisch durch „nichtsymmetrische“ N‐N‐Spaltung zu den entsprechenden Nitrilen und Iminen (siehe Schema).

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