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Coordination of 3,5‐Diisopropyl‐1,2,4‐triazolato and 5‐Phenyltetrazolato Ligands to the [K([18]crown‐6)] + Fragment: Structural Insight into the Coordination of Nitrogen‐Rich Azolato Ligands to Single Metal Centers
Author(s) -
Zheng Wenjun,
Heeg Mary Jane,
Winter Charles H.
Publication year - 2003
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200250485
Subject(s) - chemistry , fragment (logic) , stereochemistry , coordination complex , crystallography , mathematics , metal , organic chemistry , algorithm
Durch asymmetrische η 2 ‐Koordination über zwei Stickstoffdonoren binden die heterocyclischen Liganden in K([18]Krone‐6)‐diisopropyltriazolat und K([18]Krone‐6)‐phenyltetrazolat an das Kaliumion (siehe Bild). Die Verbindungen sind Beispiele für die seltene terminale η 2 ‐Koordination stickstoffreicher Azolatliganden.

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