Far‐infrared spectrum and the soft mode of ferroelectric betaine phosphite

The far‐infrared reflection spectra of betaine phosphite single crystals in the three crystallographic directions are investigated in the range from 5 to 600 cm −1 at temperatures between 203 and 323 K using a dispersive Fourier spectrometer. The dielectric function is evaluated from the complex amplitude reflection coefficient measured. In the spectrum polarized along the ferroelectric direction a soft mode of relaxation type is observed which accounts for a large part of the relevant static dielectric constant at T c = 210 K. Among the oscillator modes, which generally exhibit normal temperature dependence, there is a heavily overdamped mode at 58 cm −1 , polarized along the crystallographia a 1 axis, with anomalous damping behaviour. The damping constant decreases nearly linearly with temperature up to 323 K which is close to T = 355 K where a second phase transition is known to exist.